quote:
Originally posted by Jacques M.
Yes, Lenny, I wonder too why lanthanum was not much used.
Leitz used it for the first series of their 2/50mm Summicron (1953/54)then abandoned it.
Same thing for the first Canon 1,2/50mm, in LTM, FL and FD. And for other lenses of this 1955/60 period. Nikon too.
Strange...
I'm reading about radioactive lenses now, Jacques.
This is interesting:
There is someone who said that the nuclear plant where he worked tried to confiscate his "newer" Leica 35mm f/2 summicron due to its "radioactive contamination".
From
http://www.bnphoto.org/bnphoto/LostSites_MonaghanRadioactive.htm Thorium is derived commercially from certain monazite sands (e.g., from India). Thorium is radioactive itself, emitting alpha particles. The resulting "daughter" products of that radioactive decay series also produce both alpha and beta particles. Related rare earth such as lanthanum are often produced from the same sources, with monazite being up to 25% lanthanum. This decay process means these thoriated glass lenses can gradually become more radioactive over time, as the more highly radioactive decay products build up in the glass. This result is counterintuitive. You would expect the radioactivity to decrease over time. But after chemically purifying the thorium from its ore sources, the thorium is relatively free of these daughter products. Over time, the thorium decays, and the levels of radioactive daughter by-products builds up. Eventually a more highly radioactive equilibrium will be reached, as in the original radioactive ores. So over the years, your "hot" lenses are likely to get more radioactive rather than less. Surprise!
Lanthanum has two isotopes in its natural form, one of which is weakly radioactive. Another source of rare earths such as lanthanum is cerite, which contains the element cerium. Cheap glasses may have iron salts in them, often yielding the familiar green color of some iron salt contaminated glasses. Cerium is often added to glass to convert iron impurities into colorless compounds, yielding clear glass suitable for optical uses. Unfortunately, the rare earths include some chemically very similar elements as contaminants, many of which are mildly radioactive. The chemistry of lanthanum and its associated rare earths is so closely related that it is readily possible to have radioactive contaminants end up in the desired lanthanum salts used in making optical glasses. The amount of such contaminants could also easily vary from batch to batch, depending on the degree of contamination in the original monazite or other mineral sources being used.
I don't think that the original levels of thorium or lanthanum specified for use in these lenses [e.g., in patent filings] is the cause of their radioactivity. Later lenses of the same exact design and glass formulas, but from later batches with higher serial numbers, do not exhibit any similar degree of radioactivity. Nor do they suffer from yellow discoloration over decades of time. So it isn't the thorium or the lanthanum that causes the problem here. The radioactivity of these early lenses is caused by contaminants in the ingredients (e.g., thorium salts) used to make the early lenses. It is these radioactive contaminants which cause these lenses to be more radioactive than their later (more purified) batches of the same design.